Product ID:NITROGEN(CRYOGENIC LIQUID)
MSDS Date:08/01/1985
FSC:4470
NIIN:01-037-3819
Status Code:A
MSDS Number: CLGTB

Emergency Phone: 304-744-3487

Info Phone: 304-744-3487

Preparer: DOD/HMIS (DGSC-SSH)

Cage: 36346

Telephone: 818-341-2021

Cage: 3H796

NITROGEN

CAS: 7727-37-9

RTECS: QW9700000

Fraction By Weight: 100%

ACGIH TLV: ASPHYXIANT; 9192

Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INGEST: FROSTBITE MAY RESULT FROM
CONTACT WITH LIQUID. INHALE: ASPHYXIANT. MODERATE CONCENTRATIONS
MAY CAUSE HEADACHE, DROWSINESS, DIZZINESS, EXCITATION, EXCESS
SALIVATION, VOMITING AND UNCONSCIOUSNES S. LACK OF OXYGEN CAN CAUSE
DEATH. SKIN: CONTACT MAY CAUSE FROSTBITE.
Effects of Overexposure:INGEST: FROSTBITE MAY RESULT FROM CONTACT WITH
LIQUID. INHALE: ASPHYXIANT. MODERATE CONCENTRATIONS MAY CAUSE
HEADACHE, DROWSINESS, DIZZINESS, EXCITATION, EXCESS SALIVATION,
VOMITING AND UNCONSCIOUSNES S. LACK OF OXYGEN CAN CAUSE DEATH.
SKIN: CONTACT MAY CAUSE FROSTBITE.
Medical Cond Aggravated by Exposure:THE TOXICOLOGY AND THE PHYSICAL AND
CHEMICAL PROPERTIES OF THE MATERIAL DO NOT SUGGEST THAT
OVEREXPOSURE IS LIKELY TO AGGRAVATE EXISTING MEDICAL CONDITIONS.

First Aid:SKIN:IMMED WARM FROST BITE AREA W/WARM WATER(,105F). CALL A
PHYSICIAN. INHAL:RMV TO FRESH AIR. GIVE CPR IF NOT BREATHING. GIVE
OXYGEN IF BREATHING DIFFICULT. CALL A PHYSICIAN.EYE: IMMED FLUSH
W/WATER FOR 15 MINUTES. IMMED SEE AN OPTHAMOLOGIST.

Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:EVAC AREA. DELUGE CYL W/WATER SPRAY FM MAX
DIST UNTIL COOL.
Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE DUE TO HEAT OF
FIRE. KEEP TEMP BELOW 125F.

Spill Release Procedures:EVAC AREA. USE SCBA. SHUT OFF LEAK IF W/O
RISK. VENT AREA OF LEAK OR MOVE LEAKER TO WELL-VENT AREA. TEST AREA
FOR SUFFICIENT OXYGEN CONTENT PRIOR TO PERMITTING RE-ENTRY OF
PERSONNEL.

Handling and Storage Precautions:HIGH PRESS GAS. USE PIPING/EQUIP
DESIGNED TO WITHSTAND PRESSURE. CAN CAUSE RAPID SUFFOCATION DUE TO
OXYGEN DEFICIENCY. STORE W/ADEQUATE VENTILATION.
Other Precautions:CLOSE VALVE WHEN NOT IN USE & WHEN EMPTY. NEVER WORK
ON A PRESSURIZED SYSTEM. IF LEAKING, CLOSE CYLINDER VALVE,BLOW DOWN
SYSTEM BY VENTING TO SAFE PLACE, THEN REPAIR THE LEAK.

Respiratory Protection:NIOSH,MSHA APPROVED AIR SUPPLIED RESPIRATOR.
Ventilation:MECHANICAL ACCEPTABLE, LOCAL PREFERRED.
Protective Gloves:LOOSE-FITTING CRYOGENIC GLOVES
Eye Protection:GOGGLES
Other Protective Equipment:METATARSAL SHOES FOR CYLINDER HANDLING
Supplemental Safety and Health
NONE

HCC:G3
Boiling Pt:B.P. Text:-320F,-196C
Vapor Pres:GAS
Vapor Density:0.97
Spec Gravity:GAS
Evaporation Rate & Reference:HIGH
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
NONE CURRENTLY KNOWN
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:NONE

Waste Disposal Methods:SLOWLY RELEASE INTO ATMOSPHERE. DISCARD ANY
RESIDUE,PRODUCT,DISPOSABLE CONTAINER IN FULL COMPLIANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.